منابع مشابه
Recent advances in carbon dioxide capture with metalorganic frameworks
Uncontrolled massive release of the primary greenhouse gas carbon dioxide (CO2) into atmosphere from anthropogenic activities poses a big threat and adversely affects our global climate and natural environment. One promising approach to mitigate CO2 emission is carbon capture and storage (CCS), in which ideal adsorbent materials with high storage capacity and excellent adsorption selectivity ov...
متن کاملLuminescent metal-organic frameworks for chemical sensing and explosive detection.
Metal-organic frameworks (MOFs) are a unique class of crystalline solids comprised of metal cations (or metal clusters) and organic ligands that have shown promise for a wide variety of applications. Over the past 15 years, research and development of these materials have become one of the most intensely and extensively pursued areas. A very interesting and well-investigated topic is their opti...
متن کاملDrug delivery and controlled release from biocompatible metalorganic frameworks using mechanical amorphization
We have used a family of Zr-based metal–organic frameworks (MOFs) with different functionalized (bromo, nitro and amino) and extended linkers for drug delivery. We loaded the materials with the fluorescent model molecule calcein and the anticancer drug a-cyano-4-hydroxycinnamic acid (a-CHC), and consequently performed a mechanical amorphization process to attempt to control the delivery of gues...
متن کاملConstruction of 2-D lanthanide coordination frameworks: syntheses, structures and luminescent property{
A series of layered lanthanide coordination frameworks [Ln4(NIPH)6(H2O)4]?(4,49-bipy) [Ln = La (1), Pr (2)], [La(NIPH)2(H2O)2]?0.5(4,49-H2bipy) (3), Ln(NIPH)2(H2O)2]?0.5(4,49-H2bipy)?2H2O [Ln =Pr (4), Nd (5)], and [Ln(NIPH)2]?0.5(4,49-H2bipy) [Ln = Sm (6), Eu (7), Tb (8), Ho (9), Yb (10)] (NIPH = 5-nitroisophthalate and 4,49-bipy = 4,49-bipyridine) have been synthesized under hydrothermal condi...
متن کاملTuning the structure, dimensionality and luminescent properties of lanthanide metal-organic frameworks under ancillary ligand influence.
This manuscript addresses the synthesis, structural characterization and optical properties of a 1D coordination polymer (CPs) and 2D and 3D Metal-Organic Frameworks (MOFs) obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid (3-OHNDS) and two different phenanthroline derivates as ancillary ligands. The first is a family of 2D compounds with formula [Ln(3-OHNDS)(H2O)2], where...
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ژورنال
عنوان ژورنال: Chemical Society Reviews
سال: 2009
ISSN: 0306-0012,1460-4744
DOI: 10.1039/b802352m